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Organic Corrosion Inhibitors


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      List of Tables

      1 Chapter 5Table 5.1 Effect of substituents on the corrosion inhibition efficiency of ...Table 5.2 Chemical structures of some common amides and thio‐amides used as...Table 5.3 Chemical structures of some common Schiff bases used as corrosion...Table 5.4 Chemical structures of some common amine‐based drugs and dyes use...

      2 Chapter 6Table 6.1 Chemical structure of various imidazole derivatives calculated as...

      3 Chapter 7Table 7.1 A summary of corrosion inhibition effect of some common reports o...Table 7.2 A summary of corrosion inhibition effect of some common reports o...Table 7.3 Informations about corrosion inhibition using quinoline derivativ...Table 7.4 Informations about corrosion inhibition using 8‐hydroxyquinoline ...

      4 Chapter 8Table 8.1 Chemical structures, abbreviations, and nature of metal and elect...Table 8.2 Chemical structures, abbreviations, and nature of metal and elect...

      5 Chapter 9Table 9.1 Indole‐based compounds as corrosion inhibitors for ferrous metalsTable 9.2 Indole‐based alkaloids as corrosion inhibitors of ferrous metal.Table 9.3 Indole‐based corrosion inhibitors of nonferrous metals

      6 Chapter 12Table 12.1 Depiction of scientific findings attributable to amino acids as ...Table 12.2 Illustration of findings of the investigations related to the am...Table 12.3 Illustration of findings of the investigations related to the am...

      7 Chapter 13Table 13.1 Names and chemical structure of some drugs used as corrosion inh...Table 13.2 Names and chemical structure of some expired drugs used as corro...

      8 Chapter 14Table 14.1 ILs used to inhibit various metal corrosion in HCl medium.

      9 Chapter 15Table 15.1 Composition of fatty acids in various oils.Table 15.2 A comparison of literature on the performance of oleochemicals a...

      10 Chapter 16Table 16.1 Inhibitors, metal/electrolyte, methods applied, and outcomes of ...Table 16.2 Inhibitors, metal/electrolyte, methods applied, and outcomes of ...

      11 Chapter 18Table 18.1 Some natural polymers successfully applied to various corrosion ...

      12 Chapter 19Table 19.1 List of synthetic polymers used as corrosion inhibitor.

      13 Chapter 20Table 20.1 Abbreviations, nature of metals, electrolytes, adsorption behavi...Table 20.2 Influence of external inorganic and organic additives on anticor...

      List of Illustrations

      1 Chapter 1Figure 1.1 Corrosion cycle of steel.Figure 1.2 An electrochemical cell.Figure 1.3 Mechanism of rust formation.Figure 1.4 Classified forms of corrosion.

      2 Chapter 2Figure 2.1 Parameters of single coupon.Figure 2.2 Different shapes of metal coupons. (a) Strip/rectangular shape co...Figure 2.3 Presentation of anodic and cathodic Tafel curves and their extrap...Figure 2.4 The sinusoidal current response in a linear system on application...Figure 2.5 The making of Lissajous figure.Figure 2.6 Typical Nyquist plots for a Randles equivalent circuit with Cdl C...Figure 2.7 A typical Randles plot.Figure 2.8 Typical Bode plot.Figure 2.9 Circuit for linear polarization resistance.Figure 2.10 Gamma radiography technique for corrosion inspection, (a) tangen...Figure 2.11 Pictorial presentation of (a) generation of pulse eddy current a...Figure 2.12 Schematic diagram for generating infrared thermogram.

      3 Chapter 3Figure 3.1 Periodic boundary condition.

      4 Chapter 4Figure 4.1 A basic classification of the corrosion inhibitors.Figure 4.2 The chemical structures of the main azole compounds.Figure 4.3 The chemical structures of the main azepine compounds.Figure 4.4 The chemical structures of the main pyridine and azine compounds....Figure 4.5 The chemical structures of the main indole compounds.Figure 4.6 The chemical structures of the main quinoline compounds.Figure 4.7 The chemical structures of the green corrosion inhibitors.

      5 Chapter 6Scheme 6.1 Resonating structures of imidazole.Figure 6.1 PDP plots for the corrosion of Al in 0.5M HCl without and with va...Figure 6.2 Nyquist plots for P110 carbon steel electrode obtained in 1M HCl ...Figure 6.3 SEM micrographs for (a) blank, (b) M‐1, (c) M‐2, and (d) M‐3.Figure 6.4 Optimized structures of LMS and PIZ (HOMO/LUMO).Figure 6.5 Top view and side view of the neutral inhibitors' final adsorptio...

      6 Chapter 7Figure 7.1 FMOs of benzene, pyridine, 2‐aminopyridine, and 2,6‐diaminopyridi...

      7 Chapter 8Figure 8.1 Pictorial illustration of some major accidents that have been hap...Figure 8.2 Classification of organic corrosion inhibitors. Organic corrosion...Figure 8.3 FMOs (frontier molecular orbitals) pictures of quinoline and 8‐hy...

      8 Chapter 9Figure 9.1 Structure of indole and isatin. Structures of indole (left‐hand s...Scheme 9.1 Synthetic scheme of alum catalyzed bis(indolyl)methanes.Scheme 9.2 One‐pot oxidative Michael reaction of Baylis–Hillman adducts.Scheme 9.3 Synthetic route of bis‐Schiff bases from isatin.Scheme 9.4 One‐pot synthesis of indole‐2‐carboxylic acids.Scheme 9.5 Synthetic scheme of 2‐substituted indoles by heteroannulation.Scheme 9.6 Preparation of N‐benzyl indole aldehydes from indole.Scheme 9.7 Preparation of 3‐amino‐alkylated indoles.Scheme 9.8 Synthetic route of Boric acid and CTAB‐catalyzed indole derivativ...Figure 9.2 Nyquist (a), bode (b), and bode phase (c) spectra for CS obtained...Figure 9.3 FTIR spectra of BMP powder (a) and the barrier layer of BMP adsor...Figure 9.4 SEM‐EDX micrographs for polished Cu (a, d), the polished Cu immer...Figure 9.5 Suggested model of adsorption of bis‐Schiff bases of isatin on MS...Figure 9.6 Optimized, EHOMO and ELUMO frontier molecular orbitals of neutral...Figure 9.7 The most stable energy configuration (a) and the density field (b...

      9 Chapter 10Figure 10.1 Environmentally sustainable inhibitors for oil–gas industry.Scheme 10.1 Synthesis of chromenopyrazole derivative.Figure 10.2 Structures of some drugs and drug derivatives as corrosion inhib...Figure 10.3 Adsorption and corrosion inhibition of Metformin drug on steel s...Figure 10.4 Structure of some macrocyclic corrosion inhibitors.Scheme 10.2 Synthesis of chitosan Schiff bases for corrosion inhibition of c...Scheme 10.3 Synthesis of bis(2‐aminoethyl)amine‐modified GO (B2AA‐GO).Scheme 10.4 Synthesis of polyethyleneimine‐modified