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Table of Contents
1 Cover
4 Preface
7 2 Rational Design of Superatoms Using Electron‐Counting Rules 2.1 Introduction 2.2 Electron‐Counting Rules 2.3 Stabilizing Negative Ions Using Multiple Electron‐Counting Rules 2.4 Conclusions References
8 3 Superhalogens – Enormously Strong Electron Acceptors 3.1 Superhalogen Concept 3.2 Alternative Superhalogens 3.3 Polynuclear Systems and the Search for EA and VDE Limits 3.4 Superhalogens' Applications at a Glance 3.5 Final Remarks Acknowledgements References
9 4 Endohedrally Doped Superatoms and Assemblies 4.1 Introduction 4.2 Magic Clusters and Their Electronic Stability 4.3 Discovery of Silicon Fullerenes and Other Polyhedral Forms 4.4 Endohedral Superatoms of Ge, Sn, and Pb 4.5 Magnetic Superatoms 4.6 Endohedral Clusters of Group 11 Elements 4.7 Endohedral Clusters of B, Al, and Ga 4.8 Hydrogenated Silicon Fullerenes 4.9 Compound Superatoms and Other Systems 4.10 Assemblies of Superatoms 4.11 Concluding Remarks Acknowledgements References
10 5 Magnetic Superatoms 5.1 Introduction 5.2 The Arrival of the Magnetic Superatom 5.3 Tunable Superatoms 5.4 The Delocalisation of d‐electrons 5.5 Prospects for Nanostructured Magnetic Material Design References
11 6 Atomically Precise Synthesis of Chemically Modified Superatoms 6.1 Introduction 6.2 Electronic Structures of Chemically Modified Superatoms 6.3 Atomically Precise Synthesis of Chemically Modified Superatoms 6.4 Summary References
12 7 Atomically Precise Noble Metals in the Nanoscale, Stabilized by Ligands 7.1 Introduction 7.2 Fundamentals 7.3 Applications 7.4 Summary and Outlook References
13 8 Superatoms as Building Blocks of 2D Materials 8.1 Introduction 8.2 Fullerene‐assembled 2D Materials 8.3 Si‐based Cluster Assembled 2D Materials 8.4 Binary Semiconductor Cluster Assembled 2D Materials 8.5 Simple and Noble Metal Cluster‐assembled 2D Materials 8.6 Zintl‐ion Cluster‐assembled 2D Materials 8.7 Chevrel Cluster‐Assembled 2D Materials 8.8 Summary and Future Perspectives References
14 9 Superatom‐Based Ferroelectrics 9.1 Introduction 9.2 Organic Ferroelectrics 9.3 Hybrid Organic‐Inorganic Perovskites 9.4 Supersalts