Nirmal K. Sinha

Engineering Physics of High-Temperature Materials


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that ties it all together. Moreover, the implications of applying the knowledge to different fields is vast: from predicting/designing to account for the creep of nickel‐base turbine blades in aerospace or power engineering, to guidelines for ice fishermen about how long a vehicle can remain parked on a floating ice sheet, or even to describe certain aspects of post‐glacial uplift and plate tectonics, including man‐made reservoir‐induced earthquakes, known as reservoir‐triggered seismicity (RTS).

      The traditional concept of “strength” implies a specific material property. But the strength of a material is a low‐homologous temperature concept, say, less than about 0.3T m. This low‐temperature concept, based primarily on stress‐strain diagrams without any reference to time, does not apply at the elevated temperatures relevant to all high‐temperature engineering, for example, hot sections of gas turbine engines or nuclear and power‐generation applications. Strength at elevated temperatures is rate sensitive and is therefore not a specific property. Nonetheless, the concept of strength as a specific property (a low‐temperature concept) has retarded growth in the understanding of microstructure–property relationships and failure processes in engineering components in general. The application of this concept has misleading implications, drawing away from one basic fact: transient or primary creep stage, involving the initial periods of damage accumulation, plays a dominant and perhaps decisive role in many engineering problems. In Chapter 8, we will use the crack‐enhanced Elasto – Delayed‐Elastic – Viscous (EDEV) model for predicting the rate sensitivity of strength in a rational manner.

      One of the primary intentions of writing this text is to draw attention to the fact that polycrystalline ice can be used as an “ideal analogue” material to explain certain peculiarities of the elevated temperature response of engineered as well as natural materials. One such peculiarity is the observation that a polycrystalline material may exhibit both ductility and brittleness in a simultaneous manner. And this may happen at rather low levels of stress for engineering applications. But again, what do we mean by low or high stresses appropriate for high temperatures? Only by examining and analyzing the initiation of grain‐facet size cracks that can lead to tensile fracture can we offer a satisfactory mathematical and physical description for the stress as low or high. There is sufficient evidence to show that stresses higher than about 1 × 10−5 E at T > 0.4T m (where E is the Young’s modulus) may be considered as high stress for polycrystalline materials at high homologous temperature.

      The onset of microcracking activities in pure, transparent ice can be monitored both visually and using AE technology. This dual process of evaluation is not possible for most opaque materials like metals, ceramics, and most rocks. Since it is not possible to visually identify the tiny grain‐facet size cracks inside most engineering materials, including bubbly ice, one‐to‐one correspondence between AE or microseismic activity (MA) signals and cracks could never be made. This is the dilemma for all metallic and ceramic materials. The predicament due to the opacity of specimens in most engineering materials allows AE/MA signals, even with 3D locator systems, only for monitoring the overall crack‐damage processes. We will discuss these issues in Chapter 4 (Section 4.10) and Chapters 7 and 8 for clarifying the advantages of using pure ice as an ideal analogue material for studies on engineering materials in general.

      Sea ice in the Arctic Ocean plays one of the most important roles in modifying the climate of the world. Sea ice in the Antarctic region is marginal and seasonal, as described in our earlier book, Sea Ice: Physics and Remote Sensing (AGU/Wiley, 2015). No doubt, we must pay attention to the formation and decay of sea ice as a measure of climate change. Coincidentally, air‐ or space‐borne images of sea ice bear all the likeness of micrographs of metals, alloys, rocks, and ceramics, as pointed out in Chapter 11. Ice floes in the oceans can be characterized as grains in polycrystalline materials. On the other hand, an image of floating pack‐ice may also evoke likeness to Earth’s tectonic plates and sub‐plates. Relative movements of sea ice floes with respect to each other and rafting can be described as divergence, convergence, subduction, etc. Can we apply the lessons learned from the bearing‐capacity of floating ice, on the basis of the EDEV model, to large‐scale global phenomena such as post‐glacial uplifting (see Chapter 10), which is a very complex issue related to the convergence and subduction of plate tectonics or RTS (see Chapter 11)?

      Materialogists would perhaps give limited thought to the geophysically established fact that the secondary cryospheric zones of Earth – the Himalayas, Andes, Rockies, etc. – are products of high‐temperature phenomena active deep underneath Earth’s crust. Plate tectonics, very similar to sea ice dynamics, is briefly presented in Chapter 11. It is shown that the zone of reservoir‐induced earthquakes (or RTS), such as the Koyna–Warna area in India, may be predicted on the basis of the Elasto – Delayed-Elastic (EDE) aspect of the EDEV equation.

      Source: Visionary sketch by N.K. Sinha.

      History based on engineering physics looks to be the domain of professionals in metallurgy and materials science or materialogists. Where so much of the past, even the chronology, has to be teased from articulated intellectual objects emphasized in textbooks, scientific papers, and monographs, there surely must be need for a new perspective. However, much of the information required with state‐of‐art experimental observations was missing. The principal author, in particular, decided therefore to take a path that was a deviation from the normal.

       Nirmal K. Sinha and Shoma Sinha