A. Kayode Coker

Chemical Process Engineering Volume 1


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damages. Further, readers should be aware that websites listed in this work may have changed or disappeared between when this work was written and when it is read.

       Library of Congress Cataloging-in-Publication Data

      ISBN 9781119510185

      Cover image: Chemical Plant - Slidezero | Dreamstime.com

      Cover background: Flowing Image - Mikhail Sheleh | Dreamstime.com

      Cover design by Kris Hackerott

      Set in size of 11pt and Minion Pro by Manila Typesetting Company, Makati, Philippines

      Printed in the USA

      10 9 8 7 6 5 4 3 2 1

      Companion Web Page

      This 2-volume set includes access to its companion web page, from which can be downloaded useful software, spreadsheets, and other value-added products related to the books. To access it, follow the instructions below:

      1 Go to https://scrivenerpublishing.com/coker_volume_one/

      2 Enter your email in the username field

      3 Enter “Refining” in the password field

      Gratitude

       To the Almighty father for providing us with the abundance of nature, so that human beings can further develop and make use of the many things in nature for our well-being and for the world.

       To all process/chemical engineers worldwide utilizing this abundance of nature for the good of mankind.

       Keep the heart of your thoughts pure, by so doing you will bring peace and be happy

       To honour God in all things and to perform everything solely to the glory of God

       Abd-ru-shin (In the Light of Truth)

       A. Kayode Coker

      Dedication

       “I am always obliged to a person who has taught me a single word.”

       In memory of my late father and to my respected family for their endless support

       To engineers and scientists for their commitment to inclusion and sustainability

       R. Sotudeh-Gharebagh

      Preface

      An increased use of computational resources by engineers has greatly expedited the design of equipment and process plants in refining, and the chemical process industries. In addition, the availability of commercial and open source process simulation packages, and spreadsheets has drastically reduced the requirement of programming with high-level languages, such as BASIC, C, C++, COBOL, Java, FORTRAN and Pascal. Situations may arise where a simulation package is not readily available, too expensive or of a limited scope, in this case, hands-on tools; e.g. spreadsheets could be used to review other alternatives or develop specific programs. Furthermore, the simulation packages can be integrated with spreadsheets to enlarge their scope to equipment and process design due to the infrastructure they provide on component databases, physical property estimations and unit operations.

      A text-book, including the theory with equations, tables, and figures and the use of advanced tools is not readily available to the process designer. Our aim in preparing this text is to present theory, along with Excel spreadsheet and UniSim Design software programs for solving a wide range of design problems. The book will, therefore, benefit chemical/process engineers, students, technologists and practitioners in the petroleum, petrochemical, pharmaceutical, biochemical and fine chemical industries. The structured approaches are provided that can be used to solve a wide range of process engineering problems and thus analyze and simulate process equipment regularly.

      The process design concepts, guidelines; codes and standards are clearly important, and several excellent books and references are available to address these issues and will be cited in the book where applicable. However, these two volume-sets are unique in that to date no textbook on chemical process design and simulation has been published, which provides adequate information (theory, equations, figures, tables and programs) to enable the reader to perform robust calculations using Excel spreadsheet - UniSim Design software program. The better use of these tools in the special format shapes the core of the book as:

       – Microsoft Excel® is part of the Microsoft Office. It is widely recognized as the most versatile spreadsheet for problem solving, which enables a chemical engineer to make computation and visualizations in an easiest way possible. Process engineers can use Excel spreadsheet for equipment and process design, modeling, simulation and optimization. Data bases and pivot tables can be easily designed with Excel spreadsheet to ease making calculations, understanding technical reports, and preparing charts and figures.

       – The new improved UniSim R480 Design of Honeywell, is a smart and intuitive software; it creates thermodynamics and unit operation steady-state and dynamic models. Process simulation is a tool used to design a new process, an existing process or debottleneck, monitor process conditions, troubleshoot current operations to compare theoretical results, optimize process conditions for enhanced throughput, and to reduce energy yields, and emissions.

      1 a) All problems solved in UniSim Design can be easily converted to any units of measurement and it makes no difference which unit is used.

      2 b) The use of both units is very useful from instructional viewpoint as students need to have some sort of practice with both units as the Imperial unit is still used in some countries.

      However, since all problems are carefully solved in Excel, the conversion is then easy, and we have also provided a conversion table to assist readers in their calculations.

      The book is primarily intended to serve senior students, early career engineers, university professors and practitioners, especially in the process, chemical, petrochemical, biochemical, mechanical, mining and metallurgical industries. However, other engineers, consultants, technicians and scientists concerned with various aspects of industrial design, and scale-up may also find it useful. It can be considered as a textbook to process design for senior and graduate students as well as a hands-on document for engineers at the entry level and practitioners. The content of this book can also be taught in intensive workshops in process industries.