arylation using sulfide‐tethered bromoarene...Scheme 20.25. C–H annulation of isocyanides using haloarenes.Scheme 20.26. C–H annulation of alkynyl amides using iodoarenes.Scheme 20.27. Intramolecular C–H/Si–H coupling.Scheme 20.28. Inter‐ and intramolecular dehydrogenative couplings of diethyl...Scheme 20.29. C–H annulation of a carboxamide using an alkyne.Scheme 20.30. C–H annulation of formamides using alkynes.Scheme 20.31. Cycloisomerization of ortho‐phenylene‐tethered alkynes.Scheme 20.32. Cycloisomerization of ortho‐phenylene‐tethered propargylamines...Scheme 20.33. Desymmetric Suzuki coupling of a dichloroarene chromium comple...Scheme 20.34. Desymmetric intramolecular Heck reaction of 1,3‐diallyl chromi...Scheme 20.35. Desymmetric reduction and Suzuki coupling of a 5,8‐dibromonaph...Scheme 20.36 Desymmetric intramolecular metathesis of 1,3‐diisoproneyl chrom...Scheme 20.37. Intramolecular cycloaddition of triynes for the synthesis of m...Scheme 20.38. Intermolecular cycloaddition of diynes for the synthesis of me...Scheme 20.39. Intermolecular cycloaddition of diynes for the synthesis of pa...Scheme 20.40. Intermolecular cycloaddition of cyclic diynes for the synthesi...Scheme 20.41. Intramolecular cycloaddition for the construction of annulated...Scheme 20.42. Intramolecular cycloaddition for the construction of zigzag‐ty...Scheme 20.43. Intramolecular cycloaddition of triynes for the synthesis of t...Scheme 20.44. Intramolecular cycloaddition of diyne‐nitriles for the synthes...Scheme 20.45. Inter‐ and intramolecular cross‐couplings of dibromides with d...Scheme 20.46. Consecutive Sonogashira couplings of 2,5‐diiodo‐1,4‐dixoa[n]pa...Scheme 20.47. Enantioselective lithiation of dioxa[n]paracyclophanes using a...Scheme 20.48. Intramolecular SN2 reaction for the synthesis of cyclic trans‐...Scheme 20.49. Intramolecular allylic amination for the synthesis of cyclic t...Scheme 20.50. Intramolecular cycloaddition of a triyne for the synthesis of ...Scheme 20.51. Intramolecular cycloaddition of triynes for the synthesis of c...Scheme 20.52. Intramolecular cycloaddition of a triyne for the synthesis of ...Scheme 20.53. Intramolecular cycloaddition of triynes for the synthesis of d...Scheme 20.54. Intermolecular cycloaddition of a benzyne precursor for the sy...Scheme 20.55. Consecutive intramolecular cycloaddition of hexaynes for the s...Scheme 20.56. Intramolecular cycloaddition of triynes for the synthesis of o...Scheme 20.57. Consecutive intramolecular cycloaddition of a hexayne for the ...Scheme 20.58. Consecutive intramolecular cycloaddition of a hexayne for the ...Scheme 20.59. Consecutive intramolecular cycloaddition of a polyne for the s...Scheme 20.60. Intermolecular cycloaddition of tetraynes with diynes for the ...Scheme 20.61. Intermolecular cycloaddition of a tetrayne with a diyne for th...Scheme 20.62. Intermolecular cycloaddition of a hexayne with a diyne for the...Scheme 20.63. Intermolecular cycloaddition of tetraynes with diynes for the ...Scheme 20.64. Consecutive cycloisomerization of tetraynes for the preparatio...Scheme 20.65. Consecutive cycloisomerization of tetraynes for the preparatio...Scheme 20.66 Consecutive cycloisomerization of tetraynes for the preparation...Scheme 20.67. Consecutive cycloisomerization of diynes for the synthesis of ...Scheme 20.68 Cycloisomerization of alkynes for the synthesis of disubstitute...Scheme 20.69. Cycloisomerization of alkynes for the synthesis of substituted...Scheme 20.70 Consecutive cycloisomerization of diynes for the synthesis of c...Scheme 20.71. Condensation of fused‐cyclohexanones with arylhyrazines for th...Scheme 20.72. Oxidative homo‐coupling of arenols for the synthesis of oxa[9]...Scheme 20.73. C–H annulation of 1‐arylisoquinolines with alkynes for the syn...
21 Chapter 21Scheme 21.1 Enantioselective polymerization of various racemic monosubstitut...Scheme 21.2 Monomers and ligands used in asymmetric anionic polymerization o...Scheme 21.3 Divinyl monomer and catalysts used in enantioselective cyclopoly...Scheme 21.4 Stereospecific polymerization of cyclic olefins, and employed li...Scheme 21.5 Chiral ligands used in asymmetric alternating copolymerization o...Scheme 21.6 Enantioselective resolution homopolymerization of propylene oxid...Scheme 21.7 Catalysts used in asymmetric copolymerization of meso‐epox...Scheme 21.8 Intramolecular bimetallic mechanism for enantioselective polymer...Scheme 21.9 Asymmetric copolymerization of cyclohexane epoxide with COS medi...Scheme 21.10 Various catalysts involved in enantioselective polymerization o...Scheme 21.11 Kinetic resolution polymerization of racemic eight‐membered cyc...Scheme 21.12 Asymmetric copolymerization of various meso‐epoxides with cycli...Scheme 21.13 Enantioselective resolution copolymerization of racemic termina...Scheme 21.14 Asymmetric condensation polymerization.Scheme 21.15 Asymmetric oxidative‐coupling polymerization of 2,3‐dihudroxyna...
22 Chapter 22Figure 22.1. Classification of flow reactions in fine organic synthesis.Figure 22.2. Batch method and continuous‐flow method – from the viewpoint of...Figure 22.3. Type IV continuous‐flow enantioselective 1,4‐addition with poly...Figure 22.4 Type III continuous‐flow enantioselective 1,4‐addition and catal...Figure 22.5 Sequential continuous‐flow synthesis of the baclofen precursor....Figure 22.6. Mesoporous silica/Ni–diamine composite for continuous‐flow synt...Figure 22.7. Polymer‐bound nickel–diamine catalyst for continuous‐flow 1,4‐a...Figure 22.8. Immobilized organocatalytic continuous‐flow 1,4‐addition reacti...Figure 22.9. Continuous‐flow enantioselective 1,4‐addition reaction of aldeh...Figure 22.10. Continuous‐flow enantioselective 1,4‐addition reaction of alde...Figure 22.11. Hydroxyquinone 1,4‐addition to nitrostyrene.Figure 22.12. Continuous‐flow 1,4‐addition of ketone to nitroolefin.Figure 22.13. Quinine/benzoic acid bifunctional catalysis for enantioselecti...Figure 22.14. CPA‐containing MOF‐catalyzed enantioselective 1,4‐addition of ...Figure 22.15. Amphiphilic resin‐supported chiral diene Rh complex.Figure 22.16. Ligand–Rh/Ag nanoparticle Co‐immobilization system for continu...Figure 22.17. Asymmetric Robinson annulation.Figure 22.18. Continuous‐flow Aldol reaction with a homogeneous catalyst‐pac...Figure 22.19. Asymmetric organocatalytic Aldol reaction (Type III) in hydrop...Figure 22.20. Silica‐immobilized H8‐BINOL as a catalyst for organo‐titanium ...Figure 22.21. Polystyrene‐supported cinchona alkaloid‐derived thiourea catal...Figure 22.22. Porous carbon nanosheet/polymer hybrid‐supported chiral squara...Figure 22.23. Continuous‐flow enantioselective Henry reaction with Nd/Na het...Figure 22.24. Continuous‐flow enantioselective Strecker‐type reaction with c...Figure 22.25. Continuous‐flow hydrocyanation reaction with immobilized enzym...Figure 22.26. Type IV continuous‐flow enantioselective Mannich reaction inte...Figure 22.27. Continuous‐flow asymmetric allylboration with polymer‐supporte...Figure 22.28. Chiral NHC catalysis under continuous‐flow conditions.Figure 22.29. Continuous‐flow enantioselective Diels–Alder reaction using im...Figure 22.30. Optimization of Type III continuous‐flow reaction with the ass...Figure 22.31. Homochiral cage catalyst for continuous‐flow enantioselective ...Figure 22.32. Anchor effects in organocatalytic enantioselective cyclopropan...Figure 22.33. Continuous‐flow enantioselective C–H insertion reaction with s...Figure 22.34. Type III continuous‐flow asymmetric hydroformylation.Figure 22.35. Heterogeneous Rh catalyst immobilized on carbon by π–π interac...Figure 22.36. Continuous‐flow enantioselective α‐amination of oxindole.Figure 22.37. Photopolymerized chiral monolithic chip reactor for continuous...Figure 22.38. Type IV continuous‐flow enantioselective electrophilic fluorin...Figure 22.39. Type III continuous‐flow enantioselective electrophilic fluori...Figure 22.40. Type III continuous‐flow enantioselective photooxygenation of ...Figure 22.41. Continuous‐flow enantioselective electrochemical process.Figure 22.42. Type III continuous‐flow enantioselective sulfoxidation.Figure 22.43. Continuous‐flow kinetic resolution of racemic alcohol.Figure 22.44. Supported isothiourea catalyst in continuous‐flow kinetic reso...Figure 22.45. Continuous‐flow desymmetrization with immobilized chiral SPINO...Figure 22.46. Type III Corey–Bakshi–Shibata reductions in a microreactor sys...Figure 22.47. Type III organocatalytic enantioselective reductions of nitroe...Figure 22.48. Type III continuous‐flow asymmetric transfer hydrogenation inv...Figure 22.49. Continuous‐flow enantioselective MPV‐type reduction with suppo...Figure 22.50. Enantioselective hydrogenation of imines using supported Ir/no...Figure 22.51. Continuous‐flow organocatalytic enantioselective hydrosilylati...Figure 22.52. Supported rhodium‐catalyzed Type IV continuous‐flow enantiosel...Figure 22.53. Supported rhodium‐catalyzed Type IV continuous‐flow enantiosel...Figure 22.54. Modified Augustine approach for continuous‐flow enantioselecti...Figure 22.55. Assembling catalytic functions into single heterogeneous mater...
Guide
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