Professor Kris Heyde

Quantum Mechanics for Nuclear Structure, Volume 2


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similarly,

      q2′=−2ab*q1+(aa*−bb*)q2+2ba*q3,(1.70)

      q3′=(b*)2q1−2a*b*q2+(a*)2q3;(1.71)

      whence

      This is still a representation of an SU(2) transformation: there are no new parameters. However, it is a 3 × 3 matrix representation of SU(2). From the Euler angle parameterisation, equation (1.56),

      and substitution of these values of a and b into the matrix in equation (1.72) will yield D(1)(α,β,γ), the β-dependent part of which is given by equation (1.65).

      The process can be iterated by defining

      p1≔u13,p2≔3u12u2,p3≔3u1u22,p4≔u23,(1.74)

      which will yield a 4 × 4 matrix representation of SU(2), i.e. an expression for D(32)(R).

      Expressions for D(j)(α,β,γ) can be obtained by this process, for any j, together with the values of a and b given in equation (1.73). Likewise, D(j)(nˆ,ϕ) can be obtained using (cf. equation (1.53))

      a=cosϕ2−inzsinϕ2,b=(−inx−ny)sinϕ2,(1.75)

      where, recall, the constraint nx2+ny2+nz2=1 ensures that (nx,ny,nz,ϕ) corresponds to three free parameters. To reiterate: SU(2) is a three-parameter group.

      The representation associated with the two-component spinor (u1,u2) is called the fundamental representation. The representation associated with the three-component entity (q1,q2,q3) is a rank-2 SU(2) tensor, i.e. it is constituted from quadratic combinations of the fundamental representation. In turn, (p1,p2,p3,p4) is a rank-3 SU(2) tensor.

      Consider the general SO(3) transformation of the vector V⃗

      Vi′=∑iRi′iVi,(1.76)

      where the Vi are the Cartesian components of the vector and the Ri′i are the elements of the 3 × 3 matrix R that effects the orthogonal transformation. This can be generalised to

      Ti′j′k′⋯=∑i∑j∑k⋯Ri′iRj′jRk′k⋯Tijk⋯,(1.77)

      where the Tijk⋯ are the Cartesian components of a tensor, the rank of which is equal to the number of indices and the Ri′i are, as before, elements of the 3 × 3 matrix R. Details are clarified in the following.

      The simplest Cartesian tensor is of rank 2 and is often called a dyad or dyadic. It is formed from two Cartesian vectors, e.g.

      U⃗=(U1,U2,U3),V⃗=(V1,V2,V3),(1.78)

      Tij=UiVj,(1.79)

      of which there are nine components. Thus,

      Ti′j′=∑i∑jRi′iRj′jTij,(1.80)

      where the Tij are the nine components of the dyadic and the Ri′iRj′j are the elements of the 9 × 9 matrix that effects the underlying transformation. We note that there are still only three parameters involved in describing this (SO(3)) transformation.

      The nine components of T are reducible, i.e. they can be expressed as linear combinations that form subsets which transform among themselves under rotations. They are:

      U1V1+U2V2+U3V3=U⃗·V⃗≔T,(1.81)

      12(U2V3−U3V2)≔A1,(1.82)

      12(U3V1−U1V3)≔A2,(1.83)

      12(U1V2−U2V1)≔A3,(1.84)

      i.e.

      12(UiVj−UjVi)≔Akεijk.(1.85)

      Further,

      12(U1V2+U2V1)≔S12,(1.86)

      12(U2V3+U3V2)≔S23,(1.87)

      12(U3V1+U1V3)≔S31,(1.88)

      U1V1−13T≔S11,(1.89)

      U2V2−13T≔S22,(1.90)

      i.e.

      12(UiVj+UjVi)−13Tδij=Sij.(1.91)

      The combination U3V3−13T is excluded because

      T is a scalar product which is invariant under rotations. The Ak are the three independent components of an antisymmetric tensor: by antisymmetric we mean that they change sign under exchange of the indices. The Sij are the five independent components of a traceless second-rank tensor. The trace, ∑i=13Sii is evidently zero from equation (1.92). Note that

      UiVj=U⃗·V⃗3δij+(UiVj−UjVi)2+UiVj+UjVi2−U⃗·V⃗3δij,(1.93)

      i.e.

      UiVj=T3δij+Akεijk+δij.(1.94)

      Consider a rotation around the z-axis through an angle γ:

      cosγ−sinγ0sinγcosγ0001U1U2U3=U1′U2′U3′,(1.95)

      whence

      U1′=U1cosγ−U2sinγ,U2′=U1sinγ+U2cosγ,U3′=U3;(1.96)

      and similarly

      V1′=V1cosγ−V2sinγ,V2′=V1sinγ+V2cosγ,V3′=V3.(1.97)

      Then for the Ak,

      A1′=12U2′V3′−U3′V2′=12(U1sinγ+U2cosγ)V3−U3(V1sinγ+V2cosγ)=A1cosγ−A2sinγ;(1.98)

      similarly

      A2′=A1sinγ+A2cosγ(1.99)

      and

      A3′=A3,(1.100)

      i.e.

      cosγ−sinγ0sinγcosγ0001A1A2A3=A1′A2′A3′.(1.101)

      Evidently, we can write

      A⃗=12U⃗×V⃗.(1.102)

      Further, for the Sij,

      S12′=12(U1cosγ−U2sinγ)(V1sinγ+V2cosγ)+(U1sinγ+U2cosγ)(V1cosγ−V2sinγ)=(U1V1−U2V2)sinγcosγ+12(U1V2+U2V1)(cos2γ−sin2γ)=(S11−S22)sinγcosγ+S12(cos2γ−sin2γ)=12(S11−S22)sin2γ+S12cos2γ;(1.103)

      similarly,

      S23′=S23cosγ+S31sinγ,(1.104)

      S31′=−S23sinγ+S31cosγ,(1.105)

      S11′=−S12sin2γ+12S11(1+cos2γ)+12S22(1−cos2γ),(1.106)

      and

      S22′=S12sin2γ+12S11(1−cos2γ)+12S22(1+cos2γ),(1.107)

      i.e.

      cos2γ0012sin2γ−12sin2γ0cosγsinγ000−sinγcosγ00−sin2γ0012(1+cos2γ)12(1−cos2γ)sin2γ0012(1−cos2γ)12(1+cos2γ)S12S23S31S11S22=S12′S23′S31′S11′S22′.(1.108)

      Similar equations can be obtained for S12,S23,S31,S11,S22 for rotations about the x and y axes.

      The {Ak}, T, and the {Sij} transform separately under rotations. Dyadics are said to possess a reducible structure with respect to rotations.