Claude Cohen-Tannoudji

Quantum Mechanics, Volume 3


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to ambiguity, we will return to the full notation.

      A-5-a. Bosons: commutation relations

      Consider, for bosons, the two operators image and image. If both subscripts i and j are different, they correspond to orthogonal states |ui〉 and |uj〉. Using twice (A-16) then yields:

      (A-30)image

      Changing the order of the operators yields the same result. As the Fock states form a basis, we can deduce that the commutator of image and image is zero if ij. In the same way, it is easy to show that both operator products aiaj and ajai acting on the same ket yield the same result (a ket having two occupation numbers lowered by 1); ai and aj thus commute if ij. Finally the same procedure allows showing that ai and image commute if ij. Now, if i = j, we must evaluate the commutator of ai and image. Let us apply (A-16) and (A-22) successively, first in that order, and then in the reverse order:

      (A-31)image

      The commutator of ai and image is therefore equal to 1 for all the values of the subscript i. All the previous results are summarized in three equalities valid for bosons:

      A-5-b. Fermions: anticommutation relations

      For fermions, let us first assume that the subscripts i and j are different. The successive action of image and image on an occupation number ket only yields a non-zero ket if ni = nj = 0; using twice (A-18) leads to:

      (A-33)image

      but, if we change the order:

      (A-34)image

      If we define the anticommutator [A, B]+ of two operators A and B by:

      (A-36)image

      Taking the Hermitian conjugate of (A-35), we get:

      (A-38)image

      which can be written as:

      Finally, we show by the same method that the anticommutator of ai and image is zero except when it acts on a ket where ni = 1 and nj = 0; those two occupation numbers are then interchanged. The computation goes as follows:

      (A-40)image

      and:

      (A-41)image

      Adding those two equations yields zero, hence proving that the anticommutator is zero:

      (A-42)image

      In the case where i = j, the limitation on the occupation numbers (0 or 1) leads to:

      (A-43)image

      (A-44)image

      (A-45)image

      A-5-c. Common relations for bosons and fermions

      To regroup the results valid for bosons