Claude Cohen-Tannoudji

Quantum Mechanics, Volume 3


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      (73)image

      and the rotational energy is simply written as:

      (75)image

      (76)image

      The two velocities vl and c allow an easy comparison of the respective importance of the kinetic and potential energies in a state l.

      (78)image

      allows making interpolations between the discrete integer values of l.

      Using the normalization relation (64) of the wave function (63), we can express x as a function of |cl′ (t)|2:

      (79)image

      The other two curves in Figure 3 correspond to a much larger value of g, hence, according to (39), to a much higher value of c. There are now several values of l for which vl is small compared to c. The dashed line corresponds, as for the previous curve, to a superposition of the two states l = 1 and l′ = l — 1; the solid line (for the same value of g) to a superposition of l = 3 and l′ = 0, corresponding to the case where the system goes directly from the state l = 3 to the rotational ground state in the torus, with l′ = 0. It is obviously this last curve that presents the lowest energy barrier starting from l = 3 (shown with a circle in the figure). This is normal since this is the curve that involves the largest variation in the kinetic energy, in a sense opposite to that of the potential energy variation. It is thus the direct transition from l = 3 to l′ = 0 that will determine the possibility for the system to relax towards a state of slower rotation. Let us again use (74)