Remote C-H Bond Functionalizations. Группа авторов

      

      Table of Contents

      1  Cover

      2  Title Page

      3  Copyright

      4  1 Introduction

      5  2 Transition Metal‐Catalyzed Remote meta‐C–H Functionalization of Arenes Assisted by meta‐Directing Templates 2.1 Introduction 2.2 Template‐Assisted meta‐C–H Functionalization 2.3 Mechanistic Considerations 2.4 Conclusion References

      6  3 C–H Functionalization of Arenes Under Palladium/Norbornene Catalysis 3.1 Introduction 3.2 Pd(0)‐Catalyzed C–H Functionalization of Aryl (Pseudo)Halides 3.3 Pd(II)‐Catalyzed C–H Functionalization of Arenes 3.4 Conclusions and Outlook Acknowledgments References

      7  4 Directing Group Assisted meta‐C–H Functionalization of Arenes Aided by Norbornene as Transient Mediator 4.1 Introduction 4.2 meta‐C–H Alkylation of Arenes 4.3 meta‐C–H Arylation of Arenes 4.4 meta‐C–H Chlorination of Arenes 4.5 meta‐C–H Amination of Arenes 4.6 meta‐C–H Alkynylation of Arenes 4.7 Enantioselective meta‐C–H Functionalization 4.8 Conclusion References

      8  5 Ruthenium‐Catalyzed Remote C–H Functionalizations 5.1 Introduction 5.2 meta‐C–H Functionalizations 5.3 para‐C–H Functionalizations 5.4 meta‐/ortho‐C–H Difunctionalizations 5.5 Conclusions Acknowledgments References

      9  6 Harnessing Non‐covalent Interactions for Distal C(sp²)–H Functionalization of Arenes 6.1 Introduction 6.2 Non‐covalent Interactions in Metal Catalyzed C

H Bond Functionalization 6.3 Overview of Iridium‐Catalyzed Borylation 6.4 Non‐covalent Interactions in Ir‐Catalyzed Borylation 6.5 meta‐Selective Borylation using Non‐covalent Interactions 6.6 para‐Selective Borylation using Non‐covalent Interactions 6.7 Conclusions References

      10  7 The Non‐directed Distal C(sp²)–H Functionalization of Arenes 7.1 Introduction 7.2 C–Het Formation 7.3 C

C Bond Forming Reactions 7.4 Outlook References Note

      11  8 Transition Metal Catalyzed Distal para‐Selective C–H Functionalization 8.1 Introduction 8.2 Template Assisted para‐Selective C–H Functionalization 8.3 Steric Controlled and Lewis Acid‐Transition Metal Cooperative Catalysis 8.4 Non‐covalent Interaction Induced para‐C–H Functionalization 8.5 Conclusion and the Prospect Acknowledgments References

      12  9 Regioselective C–H Functionalization of Heteroaromatics at Unusual Positions 9.1 Introduction 9.2 Indole 9.3 (Benzo)Thiophene 9.4 Pyrrole 9.5 Pyridine