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Methodologies in Amine Synthesis


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2.8 Remote C(sp3)–H allyation of amides using organic photocatalyst.

      Source: Modified from Wu et al. [31].

Chemical reaction depicts the site-selective remote C(sp3)–H heteroarylation of amides.

      Source: Modified from Chen et al. [34].

Chemical reaction depicts the visible-light-promoted C(sp3)–H amidation and chlorination of N-chlorosulfonamides.

      Source: Modified from Quin and Yu [35].

      2.3.2 Oxidative Strategies

      2.3.2.1 1,5‐HAT via Iminyl Radicals

Chemical reaction depicts the site-specific intermolecular γ-C(sp3)–H functionalization of ketones via iminyl radicals.

      Source: Jiang and Studer [36], Morcillo et al. [37], and Davies et al. [38].

      2.3.2.2 1,5‐HAT via Amidyl and Sulfamidyl Radicals

Chemical reaction depicts the nitrogen radical mediated remote functionalization of amides and amines.

      Source: Modified from Morcillo et al. [37].

Chemical reaction depicts the amide-directed selective C-C bond formation at C(sp3)-H bonds.

      Source: Choi et al. [40] and Chu and Rovis [41].