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Solids and Surfaces: A Chemist’s View of Bonding in Extended Structures
Roald Hoffmann
A NOTE TO THE READER:
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Copyright © 1988 by Wiley-VCH Inc. All rights reserved.
Originally published as ISBN 0-89573-709-4
Published simultaneously in Canada.
No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, except as permitted under Sections 107 and 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4744. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 605 Third Avenue, New York, NY 10158-0012. (212) 850-6011, fax (212) 850-6008, E-mail: [email protected].
Library of Congress Cataloging-in-Publication Data
Hoffmann,Roald.
Solids and Surfaces: A Chemist’s View on Bonding in Extended Structures.
p. cm.
Bibliography: p.
Includes index.
ISBN 0-471-18710-0
1. Chemical Bonds 2. Surface Chemistry. 3. Solid state chemistry
I. Title.
QD471.H83 1988
541.2’24 -- dc 20
88-14288
CIP
for
Earl Muetterties
and
Mike Sienko
Preface and Acknowledgments
The material in this book has been published in two articles in Angewandte Chemic and Reviews of Modern Physics, and I express my gratitude to the editors of these journals for their encouragement and assistance. The construction of the book based on those articles was suggested by my friend M. V. Basilevsky.
My graduate students, postdoctoral associates, and senior visitors to the group are responsible for both teaching me solid state physics and implementing the algorithms and computer programs that have