afterwards the image can, if necessary, be intensified.
Green Fog.—The surface of the film shows a peculiar brilliant green or yellowish-green lustrous appearance, generally in patches, when examined by reflected light, but is more or less distinctly pink when the plate is looked through. This effect is rarely observed except when pyro-ammonia has been used as the developer, and it most frequently occurs with old plates, especially if development has been long continued or has been forced by the addition of comparatively large quantities of ammonia.
If the green fog is only slight it does not affect the prints made from the negative, but in bad cases the prints have a patchy appearance and are less deeply printed at those points where the green fog is worst. Two methods are available for the removal of green fog.
In one of these the plate, after being fixed and washed, is placed in a hypo solution of half the strength of the ordinary fixing bath, and to this hypo solution is added a very small quantity of a solution of potassium ferricyanide, and the mixture is allowed to act on the plate for some time, the dish being rocked occasionally. The green fog will gradually disappear and some more of the ferricyanide may be added, if necessary, to secure this end, but it is important to keep the proportion of ferricyanide as low as possible, otherwise the image itself will be reduced. For this reason, if it is seen or suspected that the green fog is likely to be bad, development should be carried a little farther than usual in order to allow for the slight reduction that accompanies the removal of the green fog.
The other plan is to immerse the plate in a dilute solution of ferric chloride (perchloride of iron) until the green fog has been completely bleached, then wash, first in a dilute solution of oxalic acid and afterwards in water, and finally treat with a developer, preferably ferrous oxalate. The green fog is converted into a very fine grey deposit which is almost invisible and has no appreciable effect on the printing qualities of the negative.
Black Spots may be due to particles of dirt that have been allowed to lodge on the film during one or other of the operations, or during drying. They may also be due to particles in the emulsion, and in the latter case are generally round and sharply defined.
Black Marks of the nature of irregular streaks, looking, so to speak, like black scratches, are generally due to mechanical abrasion of the film. Pressure produces a developable image similar to that produced by the action of light.
Black Bands, indistinct or nebulous at the edges, are sometimes caused during the coating of the plate with the emulsion, in which case they, as a rule, extend all the way along or across the plate. More commonly they are due to defects in the hinges of the dark slides, which may produce the bands either by allowing light to pass through, or by giving off exhalations that affect the plates if they are allowed to remain in the dark slide for a long time. If the bands are due to the hinges, they will, of course, correspond with them in position, and if the hinge is double, in the distance between them.
Transparent Bands, or bands showing less opacity than the rest of the image, are sometimes caused by exhalations from the material forming the hinges of the dark slides.
Transparent Spots if small ("pinholes"), are generally due to the presence of particles of dust on the surface of the plate when it was exposed. Prevention lies, of course, in carefully dusting the plate and the dark slide with a soft, clean, dry camel's hair brush, before putting the former into the latter. If the spots are larger and circular, they are due either to the formation of air bubbles on the surface of the plate during development, or to the presence in the film of insensitive particles.
Uneven Opacity or Density, varying gradually from one end or side of the plate to the opposite end or side, is due to uneven coating of the plate. If there is a distinctly defined patch, less opaque than the rest, the plate was not properly covered by the developing solution.
Stains.—A uniform stain, of a yellowish or brown colour, is produced when the pyro developer contains too small a proportion of sulphite or is allowed to act for a very long time. Such a stain is rarely observed with the other developers mentioned above. The pyro stain can be more or less completely removed by immersing the plate for some time, with repeated rocking, in the alum solution given above, 1 drachm of sulphuric acid being added to every 10 ounces. The plate must afterwards be well washed in soft water. Similar stains in patches may be caused by using dirty dishes or a developer that has become turbid by being frequently used.
Deep Yellow-Orange or Brown Stains, appearing gradually in patches or all over the negative, some time after it has been fixed, and washed, and dried, are due either to imperfect fixing or to incomplete washing after fixing. There is no practicable remedy.
Halation.—When the subject photographed includes some part much more brightly lighted than the rest, such as a window in an interior subject, the details of the bright part are not only lost, but the image of it seems to spread in all directions, obliterating the details of the surrounding portions. The effect is especially noticeable when the subject includes dark parts which necessitate a somewhat long exposure. A window at the end of a long dimly lighted interior, or dark trees against a bright sky are cases in point. The effect is really due to the fact that the sensitive film is not perfectly opaque, and some of the incident light passes through the film and is reflected from the back surface of the glass on to the under side of the film, producing a blurred image superposed, as it were, on the normal image formed at the surface of the film by the action of the direct light. The effect is known as "halation." It is prevented by having a perfectly opaque film, which is a condition difficult to realize in practice, and which, moreover, introduces certain other disadvantages. It is also prevented by coating the back of the plate with some substance that will absorb the rays that have passed through the film, and so prevent their being reflected back against the under side of the film. The substance used must either be opaque or must have a deep orange, brown, or red colour, and it must have the same refractive index as the glass, otherwise the reflection will not be prevented. For practical convenience it must also be easily applied and easily removed. Many substances have been recommended but nothing is so good as caramel, prepared by the action of heat on sugar. In order to get the mixture to dry completely after it has been applied, a somewhat troublesome process of purification is necessary, but caramel specially prepared for the purpose can now be obtained from dealers in photographic materials. The caramel (which is a solid substance) is dissolved in just enough water to make a thick syrup, which is carefully applied to the back of the plates in a thin layer by means of a flat brush.
If the caramel does not dry properly the solution may be thoroughly mixed with about one quarter (or more) of its weight of very finely powdered burnt sienna or burnt umber, "ground in water."
After being coated, the plates require some time to dry, and must, of course, be carefully protected from light. If the dark-room is thoroughly dark, the plates may be put up to dry in the same manner as negatives (see page 40), but if the dark-room is not suitable, some sort of drying box must be used.
After exposure and before development the backing is removed with a damp sponge; if caramel only is used in a form completely soluble in water, it need not be removed unless a developer is being used that is to be applied to several plates in succession.
REDUCTION.
When a negative is too opaque or dense it must be reduced by dissolving away part of the silver that forms the image. The same process is also applied for the removal of general fog, sometimes with a view to subsequent intensification.
The simplest solution to use for this purpose is known as the Howard Farmer reducer and is a solution of hypo mixed with a small quantity of potassium ferricyanide (red prussiate of potash).
| Ferricyanide Solution. | ||||
| Potassium ferricyanide | 1 |
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