72.106 65 0.883 Soluble 7.52 Toluene C7H8 92.14 110 0.867 0.05 2.38 Triethylamine C6H15N 101.19 89 0.728 0.02 2.4 Trifluoroacetic acid C2HFO2 114.023 72 1.489 Miscible 8.55 2,2,2‐Trifluoroethanol C2H3F3O 100.04 74 1.384 Miscible 8.56 Water H2O 18.02 100 0.998 — 78.54 Water heavy D2O 20.03 101 1.107 Miscible o‐Xylene C8H10 106.17 144 0.897 Insoluble 2.57 m‐Xylene C8H10 106.17 139 0.868 Insoluble 2.37 p‐Xylene C8H10 106.17 138 0.861 Insoluble 2.27
References
1. Professor Murov's Organic solvent table.
2. Vogel's Practical Organic Chemistry.
3. American Chemical Society, Organic Division.
List of Cooling Baths
Cooling agent | Organic solvent or inorganic salt | Temperature (°C) |
Dry ice | 1,4‐Dioxane | +12 |
Dry ice | Cyclohexane | +6 |
Dry ice | Benzene | +5 |
Dry ice | N,N‐Dimethylformamide | +2 |
Ice | Water | 0 |
Cooling agent | Organic solvent or inorganic salt | Temperature (°C) |
Liquid N2 | Aniline | −6 |
Liquid N2 | Ethylene glycol | −10 |
Liquid N2 | Cycloheptane | −12 |
Dry ice | Benzyl alcohol | −15 |
Dry ice | Ethylene glycol | −15 |
Dry ice | Tetrahydrofuran | −22 |
Dry ice | Carbon tetrachloride | −23 |
Dry ice | 1,3‐Dichlorobenzene | −25 |
Dry ice | o‐Xylene | −29 |
Liquid N2 | Bromobenzene | −30 |
Dry ice | m‐Toluidine | −32 |
Dry ice | 3‐Heptanone | −38 |
Dry ice | Pyridine | −42 |
Dry ice | Cyclohexanone | −46 |
Dry ice | Acetonitrile | −46 |
Dry ice | m‐Xylene | −47 |
Dry ice | Diethyl carbitol | −52 |
Dry ice | n‐Octane | −56 |
Dry ice | Diisopropyl ether | −60 |
Dry ice | Trichloroethylene | −73 |
Dry ice | Isopropyl alcohol | −77 |
Liquid N2 |
Butyl acetate
|