9.1 Introduction 9.2 Synthesis of Nitrogen Compounds from Chitin and Its Derivatives 9.3 Synthesis of Amines and Formamides from α‐Amino Acids 9.4 Synthesis of Nitrogen Compounds from Cellulosic Biomass Derivatives 9.5 Synthesis of Nitrogen Compounds from Lignin Derivatives 9.6 Synthesis of Nitrogen Compounds from Triglycerides and Fatty Alcohols 9.7 Conclusion References
14 10 Recent Advances in the Synthesis of Arylamines in the Light of Application in Pharmaceutical and Chemical Industry 10.1 Modern Approaches to Transition‐Metal‐Catalyzed C–N Coupling in Industry 10.2 New Methodologies in the Synthesis of Arylamines on the Brink of Industrial Application 10.3 Advances to Arylamine Formation Using Intensified and More Sustainable Process Technologies 10.4 Miscellaneous Aspects of Aromatic Amination Reactions in the World of Active Pharmaceutical Ingredients References
15 Index
List of Tables
1 Chapter 4Table 4.1 Carreira's asymmetric approach to propargylamines.Table 4.2 Synthesis of propargylamines using AspRedAm.
2 Chapter 6Table 6.1 Addition of malonates to nitroalkene 56.
List of Illustrations
1 Chapter 1Scheme 1.1 General structure of electrophilic aminating reagent.Scheme 1.2 Mechanisms of two main types of electrophilic amination.Scheme 1.3 Early examples of Cu‐catalyzed electrophilic amination.Scheme 1.4 Cu‐catalyzed electrophilic amination of organozinc reagents.Scheme 1.5 Cu‐catalyzed electrophilic amination via aryne intermediate.Scheme 1.6 Cu‐catalyzed electrophilic amination of organolithium reagents.Scheme 1.7 Electrophilic amination of arylcuprates using a NH‐oxaziridine.Scheme 1.8 Electrophilic amination via directed C–H cupration.Scheme 1.9 Cu‐catalyzed electrophilic amination of arylboronates.Scheme 1.10 Cu‐catalyzed electrophilic amination of aryl silanes.Scheme 1.11 Cu‐catalyzed electrophilic amination of silyl enol ethers.Scheme 1.12 Cu‐catalyzed electrophilic catalyzed aminoboration of styrenes....Scheme 1.13 Cu‐catalyzed electrophilic hydroamination of styrenes.Scheme 1.14 Enantioselective Cu‐catalyzed electrophilic hydroamination of st...Scheme 1.15 Enantioselective Cu‐catalyzed electrophilic hydroamination of st...Scheme 1.16 Cu‐catalyzed electrophilic amination of alkynes.Scheme 1.17 Cu‐catalyzed annulative electrophilic amination.Scheme 1.18 Cu‐catalyzed electrophilic diamination.Scheme 1.19 Cu‐catalyzed electrophilic amino‐lactonization.Scheme 1.20 Cu‐catalyzed ring‐opening amination.Scheme 1.21 Cu‐catalyzed C–H amination of heterocycles.Scheme 1.22 Electrophilic amination catalyzed by other transition metals....Scheme 1.23 Pd‐catalyzed aromatic C–H amination via electrophilic amination....Scheme 1.24 Pd‐catalyzed aliphatic C–H amination via electrophilic amination...Scheme 1.25 Ru‐catalyzed C–H amination.Scheme 1.26 Pd‐catalyzed Catellani‐type C–H electrophilic amination.Scheme 1.27 Fe‐catalyzed electrophilic amination of styrenes.Scheme 1.28 Rh‐catalyzed formation of metallanitrenes.Scheme 1.29 Rh‐catalyzed NH‐aziridination of unactivated olefins using DPH....Scheme 1.30 Rh‐catalyzed NH‐aziridination of unactivated olefins using HOSA....Scheme 1.31 Rh‐catalyzed aromatic C–H amination.Scheme 1.32 Problems with uncatalyzed electrophilic amination.Scheme 1.33 TM‐free electrophilic amination of arylboronic acids.Scheme 1.34 TM‐free electrophilic amination of arylmetals using NH‐oxaziridi...Scheme 1.35 TM‐free Prilezhaev reaction.Scheme 1.36 TM‐free Rubottom oxidation.Scheme 1.37 TM‐free NH‐aziridination of unactivated olefins.
2 Chapter 2Scheme 2.1 Radical transposition processes using nitrogen radicals.Scheme 2.2 1,5‐HAT process in HLF reaction.Scheme 2.3 Geometrical factors, polar and enthalpic effects in 1,5‐HAT proce...Scheme 2.4 Photochemical intramolecular C(sp3)–H imination of tertiary aliph...Scheme 2.5 Photoinduced aminosulfonylation of C(sp3)—H