bonds via imin...Scheme 2.7 Intermolecular remote C(sp3)–H and C–C vinylations via iminyl rad...Scheme 2.8 Remote C(sp3)–H allyation of amides using organic photocatalyst....Scheme 2.9 Site‐selective remote C(sp3)–H heteroarylation of amides.Scheme 2.10 Visible‐light‐promoted C(sp3)–H amidation and chlorination of N‐...Scheme 2.11 Site‐specific intermolecular γ‐C(sp...Scheme 2.12 Nitrogen radical mediated remote functionalization of amides and...Scheme 2.13 Amide‐directed selective C—C bond formation at C(sp3)—H bonds....Scheme 2.14 Remote amide allylation using allyl chlorides and Ni(0) cocataly...Scheme 2.15 Regioselective cross‐coupling of C(sp3)—H bonds and alkyl bromid...Scheme 2.16 Iodine‐catalyzed visible‐light mediated C–H aminations.Scheme 2.17 Imidate radical mediated β‐C–H amination of alcohols.Scheme 2.18 Remote heteroarylation of amides via sulfonamidyl radicals [55]....Scheme 2.19 Site‐specific C–H functionalization via HAT using N‐dithiocarbam...Scheme 2.20 γ‐C(sp3)–H chlorination and...Scheme 2.21 Iron‐catalyzed remote C(sp3)–H azidation of ketones via iminyl a...Scheme 2.22 Amide‐directed fluorination of C—H bonds catalyzed by iron.Scheme 2.23 Copper‐catalyzed remote arylation of C(sp3)—H bonds via amidyl r...Scheme 2.24 Enantioselective remote C–H cyanation of amines via copper‐catal...
3 Chapter 3Scheme 3.1 C—N bond formation applying N—H bonds via photo/electrochemical m...Scheme 3.2 PCET‐mediated intramolecular carbo/hyrdroamination of alkenes....Scheme 3.3 PCET‐mediated intra/intermolecular amination of alkenes. (a) Hydr...Scheme 3.4 Electrocatalytic intramolecular hydroamination of alkenes.Scheme 3.5 Electrochemical synthesis of multifunctionalized (aza)indoles. RV...Scheme 3.6 Electrochemical intramolecular oxidative amination of tri‐ and te...Scheme 3.7 Electrochemical synthesis of imidazo‐fused N‐heteroaromatic compo...Scheme 3.8 Applying hydrazonyl radical for C—N bond formation in photochemis...Scheme 3.9 Visible‐light‐enabled access to phthalazine derivatives via an am...Scheme 3.10 Photocatalytic C—N bond formation for the preparation of N‐aryli...Scheme 3.11 Mechanistic proposal for the photocatalytic synthesis of N‐aryli...Scheme 3.12 Visible‐light‐initiated tandem reaction for the synthesis of fus...Scheme 3.13 Photocatalytic intramolecular hydroamination of olefins with ami...Scheme 3.14 Photocatalytic intermolecular hydroamination of unactivated olef...Scheme 3.15 Photocatalytic intermolecular anti‐Markovnikov hydroamination of...Scheme 3.16 Photoinduced, CuCl‐catalyzed oxidative C–N coupling of anilines ...Scheme 3.17 Proposed mechanism for the photoinduced, CuCl‐catalyzed C–N coup...Scheme 3.18 Visible‐light‐induced direct C–H amination of heteroarenes with ...Scheme 3.19 Visible‐light‐mediated C–H amination of heteroarenes.Scheme 3.20 Photocatalytic dehydrogenative C–H imidation of arenes with sulf...Scheme 3.21 Photocatalytic aryl C–H amination using primary aliphatic amines...Scheme 3.22 Anodic N—H bond cleavage for aromatic C—H bond amination.Scheme 3.23 Electrochemical oxidative C–H amination of phenols.Scheme 3.24 Site‐selective aromatic C–H amination via photoredox catalysis....Scheme 3.25 Photoinduced oxidant‐free C–H amination of arenes with azoles....Scheme 3.26 Selective C–H amination of electron‐rich arenes via photoredox c...Scheme 3.27 Electrochemical ortho‐amination of aromatic C—H bonds with azole...Scheme 3.28 Direct C2‐sulfonamidation of pyrroles via visible‐light photored...Scheme 3.29 DDQ‐mediated C2‐amination of thiophenes via visible‐light photor...Scheme 3.30 Photocatalytic benzene C–H amination and hydroxylation with hydr...Scheme 3.31 Anti‐Markovnikov hydroaminations of alkenes by two component org...Scheme 3.32 Photocatalytic dehydrogenative cross‐coupling of alkenes with az...Scheme 3.33 Photoinduced oxidative [4+2] imine/alkene annulation with H2 lib...Scheme 3.34 Visible‐light‐enabled direct benzylic C(sp3)–H amination.Scheme 3.35 Benzylic C–H amination via visible‐light photoredox catalysis....Scheme 3.36 Electrochemical dehydrogenative imidation of N‐methyl‐substitute...Scheme 3.37 Electrochemical dehydrogenative imidation of N‐methyl substitute...Scheme 3.38 Light‐driven direct intramolecular C–N cross‐coupling.Scheme 3.39 Mechanistic proposal for the light‐driven direct intramolecular ...