origin in wine varies according to fermentation conditions, especially yeast strain. In general, factors that increase the fermentation rate (yeast biomass, oxygenation, high temperature, and the presence of matter in suspension) also increase the formation of higher alcohols.
TABLE 2.1 Simple Alcohols Originating from Grapes and Yeast (Ribéreau‐Gayon et al., 1982)
Formula | Name | Boilingpoint (°C) | Concentration(g/l) | Comments oralternative name |
---|---|---|---|---|
H−CH2OH | Methanol | 65 | 0.1 | Produced by hydrolysisof pectins, not fermentation |
CH 3−CH2−OH | Ethanol | 78 | 100 | |
CH 3−CH2−CH2OH | 1‐Propanol | 97 | 0.03 | |
CH 3−CHOH−CH3 | 2‐Propanol | 82 | Traces | Isopropyl alcohol |
CH 3−CH2−CH2−CH2OH | 1‐Butanol | 117 | Traces | |
|
2‐Methyl‐1‐propanol | 107 | 0.1 | Isobutyl alcohol |
|
2‐Methyl‐2‐propanol | 82 | ? | |
CH 3−CH2−CHOH−CH3 | 2‐Butanol | 99 | Traces | |
CH 3− CHOH−CHOH−CH3 | 2,3‐Butanediol | 183 | 1 | |
CH 3−CH2−CH2−CH2−CH2OH | 1‐Pentanol | 137 | Traces | |
CH 3−CH2−CH2−CHOH−CH3 | 2‐Pentanol | 119 | Traces | |
CH 3−CH2−CHOH−CH2−CH3 | 3‐Pentanol | 115 | ? | |
|
3‐Methyl‐1‐butanol | 131 | 0.2 | Isoamyl alcohol |
|
2‐Methyl‐1‐butanol | 129 | 0.05 | Active amyl alcohol |
|
3‐Methyl‐2‐butanol | 112 | ? | |
|
cis‐3‐Hexen‐1‐ol | 156 | Present only in grapes withherbaceous odors | |
CH3−(CH2)4−CH2OH | 1‐Hexanol | 158 | 0.01 | |
CH3−(CH2)3−CHOH−CH3 | 2‐Hexanol | 138 | ? | |
CH3−(CH2)5−CH2OH | 1‐Heptanol | 177 | Traces | |
CH 3−(CH2)4−CHOH−CH3 | 2‐Heptanol | 160 | ? | |
CH 3−(CH2)6−CH2OH | 1‐Octanol | 194 | ? | |
CH 3−(CH2)5−CHOH−CH3 | 2‐Octanol | 180 | ? | |
CH 3−(CH2)7−CH2OH | 1‐Nonanol | 212 | ? | |
CH 3−(CH2)6−CHOH−CH3 | 2‐Nonanol | ? | ||
CH 3−(CH2)8−CH2OH | 1‐Decanol |